Doğalgaz Dergisi 16. Sayı (Ekim 1991)

NOx (ppm) 1000 ı----- / I J \ \ \L CnHm \ \ \ NY 1\ , _____ vr---� 1--ı'- ı:CnHm (ppm) 4000 3500 3000 2500 2000 1500 1000. 500 o 800 600 400 200 � � co (ppm) 0,5 0,4 0,3 0,2 0,1 o ----------V 2 3 Fig. 1 Exhaııst gas mıcılyses /or ııat11rcıl gm cııgiııe 11=2200 RPM x=27 ıııııl!ıyde � "' co /v � I'"' 4 5 6 7 Pe {bar) s e y ra st d e i m tional low pressure gas ınıeceion . NO x concrol meehods are divided ionfc do ecvaeeleogpomr i ee smb af os er da po np lti hc ae ci ri ocnu rr roe nn ta tsut ar tae] gas enginees (1]. 2. OXIDES OF NITROGEN EMISSIONS FROM NATURAL GAS ENGINES There are six common molecular oxides oı xniidereog(NenO: Nicric oxide (Nü), nicrogen dio­ 2), nicrous oxide (N2 gen trioxide (N O), dinitro2O3), dinierogen eecraoxide (N 2O�) and dinitrogen pentoxide (N2O5). IenmapdridqitliofonrmcwuoladNiffOerent opixes have ehe 3 , but they ar sepn ec cstpr oe scci eosp ai cnadl l yh.aTv eh eo nc wl y o bme eons ti dc e e o n m e t ra i m f n ı o e si n d ­ dmeo(lNe cOu f)aar nodx indi et rs oigneenxdhiaouxsitdae r(eNnOi t r i c o x i ­ 2). refore the term NO Thex in primarily ehe sum of ehese ewo principal nicrogen oxides NO + NO, = NOX Nt e di e r icchoexmi di el urmeaci ne se swc ei tnht o zaonnael yi zne erh. e Th ehai s analyzer is used co deeermine ehe concene- _ rr eaat icoc ni o no feNm Oi e sx l ii gn hatn, we xhhi cahu si st ms c er ea as umr e. dT bh ye a deeeccor. The intensiey oflighe produced risicporoxpidoertiinoneahlecosaemheplceoncemration of nieNO + 03 = NO2 + 02 + light Tt ehl ye cc oa nn cbe me mr aee ai os nu roefdNbOy aa ncdh eNmOi lxu sme pi na er as ­ cem analyzer. The sample passes from ehe hv ee racceerd hsealmd pa lt ea ! iena emepherroaut ug rhe ao ft haeprpmr oa xl icmo na ­ tely 660°C in ehe NO X mode. The NOı is cr eoancvceerdc ewd i ct ho No zOo n, ea nr od gc hi veen ae ht oet taol tNa l ONO i s lue. The sample scream bypasses ehe xehvear mt e ac tl ecdo ni vne re eheed Ne oONmO oidn ee .h Te hs ae mdpi fl feeirse dn ce e becween ehe NOx and NO is ehe N02 cetration. For NO conx measurements in ehe ee xxchraauc esecdgfarsosme s ,e he he ee xs ahma upslees ci rs ecaomn teihn uo s l y rough s Ta a h m h e e p a s l a e e e m d i p s s l c a e o m p n p a v s l e s e r e rs ! e i e d n h e r r . o o A u e g hh p e o h i r n e c a i s o e e e r n u d m o p f e u c n m h rs i p s . and a heared glass fiber fıleer. et hi oenr mo af le hc oe nsvaemr cpe lre we hi rehn e hg oe ees xAeche s s r s m o u ra o g l l h v p e e o n h r e e ­ . Ar efmr eorveehde wt hi rehr ma acl ocl odntvrearpr .e rT, he eh ec lwe aant edr riys ws ahme pr el ei t e hi se mn iexme de rws iethhe orzeoancee ifoonr scuhba sme qbue r ee hn et reexahc ae iuosne . sTa omt apll eNiOs xa cdoinr ec ce rn tmr aetai os un rien mc uerma c iseus b. jTe chce r No sOc a nc do anrcde nmt reaa ts iuorne mi s e anlts oa ca direct measuremene, bue it is subjece to ehe eransienr racio ofNO co NO 2 haust. NO in ehe ex2 concentrations, in addition eo being subject to ehe transienr ratio ofNO co NO 2, w e e n t waor er eolbaeeai ivneeldy al as reghee vd ai flfue er es n, ceeasc hb eoc f 25

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